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|
Office |
E-mail |
| Instructor |
薛景中 |
中研院應科中心411B |
shyue at gate.sinica.edu.tw |
| Textbook |
G. Friedbacher and H. Bubert, Surface and Thin Film Analysis: A Compendium of Principles, Instrumentation, and Applications, Second, Completely Revised and Enlarged Edition, 2011, Wiley-VCH. DOI: 10.1002/9783527636921
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| References |
J.I. Goldstein, D.E. Newbury, P. Echlin, D.C. Joy, C.E. Lyman, E. Lifshin, L. Sawyer and J.R. Michael, Scanning Electron Microscopy and X-ray Microanalysis, 4th ed., 2018, Springer. DOI: 10.1007/978-1-4939-6676-9
T.L. Alford, L.C. Feldman and J.W. Mayer, Fundamentals of Nanoscale Film Analysis, 2007, Springer. DOI: 10.1007/978-0-387-29261-8
J.C. Vickerman and I.S. Gillmore, Surface Analysis – The Principal Techniques, 2nd ed., 2009, John Wiley & Sons. DOI: 10.1002/9780470721582
The Surface Science Society of Japan, Compendium of Surface and Interface Analysis, 2018, Springer. DOI: 10.1007/978-981-10-6156-1
J.C. Rivière and S. Myhra, Handbook of Surface and Interface Analysis: Methods for Problem-Solving, 2nd ed., 2009, CRC Press. ISBN: 978-0-8493-7558-3
E. Meyer, H.J. Hug, R. Bennewitz, Scanning Probe Microscopy – The Lab on a Tip, 2004, Springer. DOI: 10.1007/978-3-662-09801-1
F. Ernst and M. Rühle, High-Resolution Imaging and Spectrometry of Materials, 2003, Springer. DOI: 10.1007/978-3-662-07766-5
J. O’Connor, B.A. Sexton, R.St.C. Smart, Surface Analysis Methods in Materials Science, 2003, Springer. DOI: 10.1007/978-3-662-05227-3
D.P. Woodruff, T.A. Delchar, Modern Techniques of Surface Science, 2nd ed., 1994, Cambridge. DOI: 10.1017/CBO9780511623172
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| Website |
http://www.shyue.idv.tw/electron_spectroscopy.php
https://es-shyue.rcas.sinica.edu.tw/
http://es.shyue.idv.tw/
|
| Workload |
Homework, 2 in total |
20% each |
40% |
| Mid-Term Exam |
30% |
30% |
| Final Exam |
30% |
30% |
| Total* |
|
100% |
* If the final class average falls below 70%, a curved scale will be used, with the class average set at or near 78%.
Homework Policies:
Homework will be due in class at the second class meeting after it is assigned. Late homework will be subject to a penalty of 10% per day unless an extension has been arranged with the instructor prior to the due date. No late homework will be accepted after a solution set has been made available.
Homework must be hand-written, hand-drawing and legible, with questions answered in numerical order, and stapled if more than one page long. Please: no spiral-bound paper, or pages connected by folding the corners. Students may consult with one another on the homework, but what is handed in must be each student's original, individual work. Homework assignments (or portions thereof) from different students that appear to have been copied or that otherwise appear to be identical may be returned to all the submitters with zero credit.
The purpose of the homework is to illustrate, apply, and reinforce key topics, not to serve as dry runs for exams.
Exam Policies:
Students may bring pencils or pens, erasers, calculators and straight edges to the tests. The mid-term and final exam will be open-book and open-notes. Computer/Pad is also allowed. However, internet and communication softwares/devices in any form are not allowed. During the 3 h exam time, students are not allowed to discuss/consult with anyone and what is handed in must be each student's original, individual and hand-written (hand-drawing) work. If there is any hint that the content is copied, zero credit will be given.
Mid-term exam will cover the lectures and reading assignments from the preceding parts of the course. The final exam will cover material from throughout the course. Some of the test questions will be similar to the homework problems in style (i.e., short-answer; calculations; explanations of concepts), but some questions will require the student to apply previous material to new situations.
Unless for definitions, memorizing (complicate) equations is not required because one can always look it up. However, understanding the correlation between factors and the physics behind is crucial.
Syllabus
Lecture topics, readings, and dates of homework assignments are subject to change and slides may be updated as we go along. Tests will cover the lecture content and the reading assignments.
| Week |
Date |
Lecture Topic |
Slide |
Recording |
| 1 |
9/3* |
Introduction and Overview: Surface Analysis;
Supplementary: Useful References and Tools; Common Mechanisms and Examples of Analytical Techniques |
[PDF] [MP4]
2024/08/19 |
00
01 02 03 04 05
2024/08/19 |
| Supplementary |
Vacuum System |
[PDF] [MP4]
2024/08/19 |
01 02 03 04
2024/08/19 |
| Sample Preparation |
[PDF] [MP4]
2024/08/19 |
01
2024/08/19 |
| Utilities and Environmental Requirements for Instruments |
[PDF] [MP4]
2024/08/19 |
01 02 03
2024/08/19 |
| 2 |
9/10 |
Photoelectron Spectroscopy (PES);
Supplementary: Introduction; Photon Sources; 2D Detectors |
[PDF] [MP4]
2024/09/06 |
01 02 03 04 05 06 07 08 09 10 11
2024/09/06 |
| 3 |
9/17 |
PES: X-ray Photoelectron Spectroscopy (XPS, a.k.a. Electron Spectroscopy for Chemical Analysis, ESCA) |
| 4 |
9/24* |
PES: Ultraviolet Photoelectron Spectroscopy (UPS) |
| 5 |
10/1 |
Quantitative XPS; HArd X-ray PES (HAXPES) |
[PDF] [MP4]
2024/09/19 |
01 02 03 04 05 06
2024/09/19 |
| 6 |
10/8* |
Angle-Resolved XPS (ARXPS);
Supplementary: Applications |
| 7 |
10/15 |
Sputter Depth Profile;
Supplementary: General Concept; Ion Optics; Examples |
[PDF] [MP4]
2024/10/07 |
01 02 03 04 05 06 07 08 09
2024/10/07 |
| 8 |
10/22* |
Supplementary: Effect of Temperature; Data Processing; (Near-)Ambient Pressure XPS;
Inverse Photoemission Spectroscopy (iPES)
Homework #1 assigned
|
| 9 |
10/29 |
Mid-Term Exam; Homework #1 due
|
| 10 |
11/5 |
Scanning Electron Microscopy (SEM); Low-Voltage and Low-Vacuum Operations
Supplementary: Sample Preparation |
[PDF] [MP4]
2024/10/30 |
01 02 03 04 05 06 07 08 09 10
2024/10/30 |
| 11 |
11/12* |
SEM related techniques: Electron Backscatter Pattern (EBSP); Electron Beam Induced Conductivity (EBIC); Cathodoluminescence (CL), etc.
Supplementary: Image Processing; Ultrafast SEM; Multi-Beam SEM; Alignment |
| 12 |
11/19 |
Auger Electron Spectroscopy (AES);
Supplementary: Introduction |
[PDF] [MP4]
2024/11/13 |
01 02 03 04 05 06 07
2024/11/13 |
| 13 |
11/26* |
Sputter Depth Profile; Scanning Auger Microscopy (SAM);
Supplementary: Processing Depth Profile |
| 14 |
12/3 |
Electron Probe Microanalysis (EPMA): X-ray Wavelength Dispersive Spectroscopy (XWDS) |
[PDF] [MP4]
2023/11/30 |
01 02 03 04 05 06 07 08
2023/11/30 |
| 15 |
12/10* |
EPMA: X-ray Energy Dispersive Spectroscopy (XEDS);
Supplementary: EPMA in TEM; Mapping and Image Processing
Homework #2 assigned |
| 16 |
12/17 |
Final Exam; Homework #2 due
|
| Supplementary |
Surface (2D) Crystallography; Low Energy Electron Diffraction (LEED); Reflection High Energy Electron Diffraction (RHEED); Dynamic (ns) and Ultrafast (fs) Electron Diffraction |
[PDF] [MP4]
2021/10/12 |
01 02 03 04 05
2021/11/13 |
| (Reflection) Electron Energy Loss Spectroscopy ((R)EELS); Electron Spectroscopic Imaging, Low-Energy/PhotoEmission Electron Microscopy (LEEM/PEEM) |
[PDF] [MP4]
2021/11/24 |
01 02 03 04 05 06 07 08 09 10 11
2021/11/24 |
*Physical discussion session in assigned classroom.
Rubric
|
Excellent |
Satisfactory |
Needs work |
Surface analysis and surface science |
Sensitivity as a function of spatial resolution |
- Sensitivity of different techniques
- Strength of different techniques
- Physical limitation
|
|
None of the above |
Adsorption of molecules on surfaces |
- Collision rate
- Thermal desorption techniques
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|
None of the above |
Vacuum system |
- Selection of vacuum components
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- Category of vacuum pumps
- Vacuum gauges
|
None of the above |
General considerations |
- Environment and utilities
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|
None of the above |
Photoemission Spectroscopy (PES) |
X-ray Photoelectron Spectroscopy (XPS) |
- Pass energy and operation of analyzer/detector
- Spectral features in XPS
- Final-state effect
- Chemical shift
- Quantitative analysis
- Angle-resolved XPS
|
- Photoelectric effect
- Instrumentation
- Definition of kinetic energy of photoelectron
- Sampling depth
- Position of Auger peak
- Qualitative analysis
- Depth profile
|
None of the above |
Sputter Depth Profile |
- Cluster ion sputtering
- Factor analysis
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- Ion sputtering
- Preferential sputter and artifacts
|
None of the above |
Ultra-violet Photoelectron Spectroscopy (UPS) |
- Angle-resolved UPS
- Valence band spectrum
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- Angle-integrated UPS
- Work function determination
|
None of the above |
Inverse Photoemission Spectroscopy (iPES) |
|
|
None of the above |
Electron Diffraction |
Surface crystallography |
- Ten 2D point groups
- Seventeen 2D space groups
|
- Five 2D lattices
- Wood’s notation and matrix notation
|
None of the above |
Low-Energy Electron Diffraction (LEED) |
- Reciprocal lattice in 2D
- Spot-Profile-Analysis LEED
- I(V)
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- Electron diffraction
- Ewald construction for LEED condition
|
None of the above |
Reflective High-Energy Electron Diffraction (RHEED) |
- Source and application of intensity oscillation
|
- Ewald construction for RHEED condition
|
None of the above |
Electron backscatter diffraction (EBSD) |
|
|
None of the above |
Scanning Electron Microscopy (SEM) |
General SEM |
- Magnification and raster size
- Instrumentation
- Resolution limitation
- Operation modes for objective lens
|
- Signal generation
- Depth of focus
- Resolution vs. current
- Kinetic energy of electrons
|
None of the above |
SE and BSE imaging |
- Yield of SE and BSE
- Low-vacuum and environmental SEM
- Effect of instrumental parameters on the image
- Signal processing
|
- Classification of SE
- Contrast in SE and BSE imaging
- Operation of detectors
|
None of the above |
Advanced operation |
- Channeling pattern
- Time-resolved SEM
|
|
None of the above |
(Reflection) Electron Energy Loss Spectroscopy (REELS) |
Inelastic scattering |
- Different types of inelastic scattering
|
- Plasmon, phonon
- Continuous energy loss
|
None of the above |
Spectrum |
- Inner-shell ionization: ELNES and EXELFS
- Quantitative EELS: partial ionization cross-section
- Background substraction
|
- Zero-loss peak
- Low-loss region
- High-loss region
- Shape of adsorption edge
- Qualitative EELS
|
None of the above |
Electron Spectroscopic Image |
- Energy-filtered diffraction
- Two- and three-window technique
- Electron tomography
|
- Zero-loss filtering
- Electron Spectroscopic Imaging
- Detection limit and spatial resolution of ESI
|
None of the above |
Auger Electron Spectroscopy (AES)
Scanning Auger Microscopy (SAM) |
- Two-electron de-excitation
- Coster-Kronig transition
- Operation mode of energy analyzer
- Quantitative analysis
|
- Nomenclature
- Differential analysis
- Chemical shift
- Instrumentation
- Charge consideration
- Qualitative analysis
- Schemes of depth-profile
|
None of the above |
Electron Probe Microanalysis (EPMA) |
General |
- Inner-shell ionization by electron or high-energy particle
- X-ray fluorescence yield
- Interaction volume (lateral and depth distribution)
- Effect of beam energy
- Quantitative analysis (ZAF correction)
|
- Characteristic x-ray and bremsstrahlung
- Selection rule of x-ray generation
- Qualitative analysis
- Accuracy of standard-less quantification
- X-ray imaging
|
None of the above |
X-ray Wavelength Dispersive Spectroscopy |
- Selecting crystals for XWDS
|
- Fully focused x-ray spectrometer
- Maximizing signal intensity
|
None of the above |
X-ray Energy Dispersive Spectroscopy |
- Principle of Si(Li) and SDD
- Processing time and dead time ratio
|
- Principle of pulse processing
- Role of collimater
- Detection solid angle
- Energy resolution of XEDS
- Artifacts in XEDS
|
None of the above |
Last update: 2024/09/03 |